Carbon-13 and proton nuclear magnetic resonance analysis of shale-derived refinery products and jet fuels and of experimental referee broadened-specification jet fuels

A proton and carbon-13 nuclear magnetic resonance (NMR) study was conducted of Ashland shale oil refinery products, experimental referee broadened-specification jet fuels, and of related isoprenoid model compounds. Supercritical fluid chromatography techniques using carbon dioxide were developed on a preparative scale, so that samples could be quantitatively separated into saturates and aromatic fractions for study by NMR. An optimized average parameter treatment was developed, and the NMR results were analyzed in terms of the resulting average parameters; formulation of model mixtures was demonstrated. Application of novel spectroscopic techniques to fuel samples was investigated

Mesospheric Temperature Variability and Seasonal Characteristics Over the Andes

The Utah State University CEDAR Mesospheric Temperature Mapper (MTM) is a high-quality CCD imager capable of remote sensing faint optical emissions from the night sky to determine mesospheric temperature and its variability at an altitude of ~87 km. The MTM was operated at the new Andes Lidar Observatory (ALO)located at Cerro Pachon, Chile (30.2° S, 70.7° W) since August 2009 to investigate the seasonal characteristic of the mesopause at mid-latitudes. Measurement were made alongside a powerful lidar capable of height sounding the mesosphere. In this study, the MTM data have been analyzed to determine night to night variability and seasonal characteristics in the OH mesospheric intensity and temperature induced by acoustic-gravity waves and atmospheric tides

The First Ten Months of Investigation of Gravity Waves and Temperature Variability Over the Andes

The Andes region is an excellent natural laboratory for investigating gravity wave influences on the Upper Mesospheric and Lower Thermospheric (MLT) dynamics. The instrument suite that comprised the very successful Maui-MALT program was recently re-located to a new Andes Lidar Observatory (ALO) located at Cerro Pachon, Chile to obtain in-depth seasonal measurements of MLT dynamics over the Andes mountains. As part of the instrument set the Utah State University CEDAR Mesospheric Temperature Mapper (MTM) has operated continuously since August 2009 measuring the near infrared OH(6,2) band and the O2(0,1) Atmospheric band intensity and temperature perturbations. This poster focuses on an analysis of nightly OH temperatures and the observed variability, as well as selected gravity wave events illustrating the high wave activity and its diversity

Observations of Mesospheric Temperature Variability Over the Andes

Observations of mesospheric OH(6,2) rotational temperatures by the Utah State University Mesospheric Temperature Mapper (MTM) located at the Andes Lidar Observatory, Cerro Pachon, Chile (30.3°S, 70.7°S) reveal a large range of nightly variations induced by atmospheric gravity waves and tides, as well as strong seasonal oscillations. This study investigates MTM temperature variability over the past 3.5 years comprising over 800 nights of high-quality data and compares the results with ground-based spectrometric measurements from nearby El Leoncito Observatory, Argentina, Maui-MALT, Hawaii MTM measurements (2001-2005) and coincident mesospheric temperature measurement by SABER on the NASA TIMED satellite

Isochronal annealing effects on local structure, crystalline fraction, and undamaged region size of radiation damage in Ga-stabilized δ\delta-Pu

The effects on the local structure due to self-irradiation damage of Ga stabilized $\delta$-Pu stored at cryogenic temperatures have been examined using extended x-ray absorption fine structure (EXAFS) experiments. Extensive damage, seen as a loss of local order, was evident after 72 days of storage below 15 K. The effect was observed from both the Pu and Ga sites, although less pronounced around Ga. Isochronal annealing was performed on this sample to study the annealing processes that occur between cryogenic and room temperature storage conditions, where damage is mostly reversed. Damage fractions at various points along the annealing curve have been determined using an amplitude-ratio method, standard EXAFS fitting, and a spherical crystallite model, and provide information complementary to previous electrical resistivity- and susceptibility-based isochronal annealing studies. The use of a spherical crystallite model accounts for the changes in EXAFS spectra using just two parameters, namely, the crystalline fraction and the particle radius. Together, these results are discussed in terms of changes to the local structure around Ga and Pu throughout the annealing process and highlight the unusual role of Ga in the behavior of the lowest temperature anneals.Comment: 13 pages, 10 figure

Satellite and Ground-Based Measurements of Mesospheric Temperature Variability Over Cerro Pachon, Chile (30.3° S)

— Observations of mesospheric OH (6,2) rotational temperatures by the Utah State University Mesospheric Temperature Mapper (MTM) located at the Andes Lidar Observatory, Cerro Pachon, Chile (30.3◦ S, 70.7◦ W) reveal a large range of nightly variations induced by atmospheric gravity waves and tides, as well as strong seasonal oscillations. This study investigates MTM temperature variability over the past 4 years comprising over 800 nights of high-quality data and compares the results with MTM measurements from Maui, Hawaii (2001-2005) and coincident mesospheric temperature measurement by the SABER instrument on the NASA TIMED satellite

Nature of oxygen at rocksalt and spinel oxide surfaces

The chemical environment of oxygen in cobalt-containing metal oxides with compositions M xM′( x – 1) O and M xM′(3x – 1) O4 (M,M′ = Mn,Ni,Co) has been studied by Auger, x-ray and ultraviolet photoelectron, and high resolution electron energy loss spectroscopies. While there is a single type of lattice oxygen in the bulk structure of simple rocksalt and spinel oxides, the nature of oxygen at the surface of the spinel oxides is considerably more complex. Photoemission from core oxygen states in these materials often shows multiple peaks and satellite structure which have been attributed to a range of intrinsic and extrinsic oxygen states. All of these 3d transition metal oxides show a single, intense O 1s core photoemission peak at approximately 529.6 eV. In the spinel materials, a second state at 531.2 eV is also observed and is shown to be intrinsic to the spinel surface and not a result of hydroxylation or other surface contaminant. Similar photoemission features in Fe3O4 were previously attributed to final state effects; however, the nature of the multiple final states remains to be elucidated